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enantioselectivity

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MECHANISTIC INSIGHTS ON RHODIUM-CATALYZED ENANTIOSELECTIVE ALLYLIC ALKYLATION FOR QUATERNARY STEREOGENIC CENTERS

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(AGENPARL) – LONDON (UNITED KINGDOM), mar 15 dicembre 2020 Installing quaternary stereogenic carbon is an arduous task of contemporary importance in the domain of asymmetric catalysis. Among these, an asymmetric allylic alkylation of α,α-disubstituted aldehydes by using allyl benzoate in the presence of Wilkinson’s catalyst [Rh(Cl)(PPh3)3], (R)-BINOL-P(OMe) as the external......

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