Agenparl

chiral

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SYNTHESIS, APPLICATION AND MOLECULAR MODELING STUDY OF IONIC LIQUID FUNCTIONALIZED LACTOBIONIC ACID, 3-METHYL-1-(3-SULFOPROPYL)-1H-IMIDAZOL-3-IUM LACTOBIONATE, AS CHIRAL SELECTOR IN CAPILLARY ELECTROPHORESIS

Redazione
(AGENPARL) – LONDON (UNITED KINGDOM), mer 21 ottobre 2020 Recently, ionic liquids have been widely used for chiral separation. However, several papers have reported the use of ionic liquids as the sole chiral selector. In this work, a novel capillary electrophoresis method using the ionic liquid 3-methyl-1-(3-sulfopropyl)-1H-imidazol-3-ium lactobionate (MSI-LA) as......
Agenparl English Educazione Scienza e Tecnologia Social Network

SELECTIVITY AND BIO-COMPATIBILITY OF SELF-ASSEMBLED CHIRAL FLOWER-LIKE AND HELICAL NANOSTRUCTURES

Redazione
(AGENPARL) – LONDON (UNITED KINGDOM), sab 26 settembre 2020 The molecular building block NDI-LCA was synthesized by substitution of NDA at di-imide position with two lithocholic acid moieties. It was found that the NDI-LCA conjugate exhibits good thermal stability. The photophysical such as UV-vis and fluorescence spectral measurements and theoretical......
Agenparl English Educazione Scienza e Tecnologia Social Network

CONSTRUCTION OF A CHIRAL ARTIFICIAL ENZYME USED FOR ENANTIOSELECTIVE CATALYSIS IN LIVE CELLS

Redazione
(AGENPARL) – LONDON (UNITED KINGDOM), mer 23 settembre 2020 Nanozymes as a newcomer of artificial enzyme family, have shown several advantages over natural enzymes such as their high stability in harsh environments, facile production on large scale, long storage time, low costs, and more resistant to biodegradation. However, compared with......
Agenparl English Educazione Scienza e Tecnologia Social Network

THREE DECADES OF DISPARLURE AND ANALOGUE SYNTHESIS

Redazione
(AGENPARL) – LONDON (UNITED KINGDOM), lun 14 settembre 2020 In this review, we have described various syntheses of disparlure (a sex pheromone emitted by female gypsy moth), its stereoisomers and analogues over the last three decades (1989−2020). The vast literature, chemical modifications and continuing interest in synthesis and bioactivity study......
Agenparl English Educazione Scienza e Tecnologia Social Network

LABORATORY BLUEPRINTS FOR INTERSTELLAR SEARCHES OF AROMATIC CHIRAL MOLECULES: ROTATIONAL SIGNATURES OF STYRENE OXIDE

Redazione
(AGENPARL) – LONDON (UNITED KINGDOM), lun 14 settembre 2020 The tracking of symmetry-breaking events in space is a long-lasting goal of astrochemists, aiming at an understanding of homochiral Earth chemistry. One current effort at this frontier aims at the detection of small chiral molecules in the interstellar medium. For that,......
Agenparl English Educazione Scienza e Tecnologia Social Network

ASYMMETRIC ALLYLIC SUBSTITUTION-ISOMERIZATION TO AXIALLY CHIRAL EN-AMIDES VIA HYDROGEN-BONDING ASSISTED CENTRAL-TO-AXIAL CHIRALITY TRANSFER

Redazione
(AGENPARL) – LONDON (UNITED KINGDOM), lun 07 settembre 2020 Axially chiral enamides bearing a N-C axis have been recently studied and were proposed to be valuable chiral building blocks, but a stereoselective synthesis has not been achieved. Here, we report the first enantioselective synthesis of axially chiral enamides via a......

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